王石,王琳,尹晓伟.激光熔覆FeCoCrNiNb高熵合金涂层组织及力学性能[J].稀有金属材料与工程,2023,52(4):1483~1489.[Wang Shi,Wang Lin,Yin Xiaowei.Microstructure and mechanical properties of laser cladding FeCoCrNiNb high entropy alloy coating[J].Rare Metal Materials and Engineering,2023,52(4):1483~1489.]
激光熔覆FeCoCrNiNb高熵合金涂层组织及力学性能
投稿时间:2022-11-11  修订日期:2022-12-07
中文关键词:  高熵合金  激光熔覆  Laves相  纳米压痕  耐磨性
基金项目:国家自然科学基金资助(62001312)
中文摘要:
      采用激光熔覆技术在304不锈钢表面制备了FeCrCoNi、FeCrCoNiNb等摩尔比高熵合金熔覆层,研究了Nb元素对熔覆层组织及性能的影响。采用XRD、SEM、EDS、纳米压痕测试和王府干滑动摩擦磨损实验等方法,纤细分析了两种高熵合金熔覆层线组成、组织演变、纳米硬度及磨损行为及磨损机理。结果表明:FeCrCoNiNb高熵合金熔覆层相组成为FCC固溶体及富Nb-Laves相。FeCrCoNiNb熔覆层的纳米硬度(H)、弹性模量(H)、H/E和H3/E2分别为6.066GPa、231.54GPa、0.0262和0.0042,远高于FeCrCoNi熔覆层的3.456GPa、209.48GPa、0.0165和0.00094。随着纳米硬度的增加,FeCrCoNiNb熔覆层的摩擦系数和比磨损率也随之降低,分别为0.519和2.54×10-6mm3/N.m。综上所述,FeCrCoNiNb高熵合金熔覆层具有良好的纳米硬度和磨损性能。
Microstructure and mechanical properties of laser cladding FeCoCrNiNb high entropy alloy coating
英文关键词:High entropy alloy  Laser cladding  Laves phase  Nanoindentation  wear
英文摘要:
      A FeCrCoNiNb high entropy alloy (HEA) coating was deposited by laser cladding, aiming at studying the influence of Nb addition on hardness and wear resistance. The formed phases, microstructural evolution, nano-hardness and wear behavior of the FeCrCoNiNb HEA coating was clarified by using XRD, SEM, nano-hardness measurement and friction-wear measurement. The results showed that the FeCrCoNiNb high-entropy alloy coating were composed by FCC solid solution and Nb-Laves phase. The nano-hardness (H), elastic modulus (H), H/E and H3/E2 of FeCrCoNiNb coating were 6.066GPa, 231.54GPa, 0.0262 and 0.0042, respectively. Which were much higher than FeCrCoNi coating of 3.456GPa, 209.48GPa, 0.0165 and 0.00094. With the increased of nano-hardness, the friction coefficient and specific wear rate of FeCrCoNiNb coating also decreased, which were 0.519 and 2.54×10-6mm3/N.m, respectively. The addition of Nb can effectively improve the nano-hardness and wear resistance of FeCrCoNi high-entropy alloy coating.
作者单位E-mail
王石 沈阳工程学院机械学院 wangshisie@163.com 
王琳 沈阳工程学院机械学院  
尹晓伟 沈阳工程学院机械学院  
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