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Effect of Oxygen Impurity and Overheating on Microstructure and Mechanical Properties of As-cast Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_5 Bulky Glass Alloys
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TG139

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    Abstract:

    Zr52. 5Cu17. 9Ni14.6Al1.0Ti5 bulky glass sheets with thickness of 2mm were prepared by a water-cooled copper mold casting. The volume fraction of quenched-in crystallines were controlled by changing oxygen impurity content and overheating level. The results show: low oxygen content and enough large overheating level can improve the glass formation ability of the present ahoy. Fully amorphous sheet with a thickness of 2mm displays high fractured strength (1 710MPa). Samples with volume fraction of 2% still have high fractured strength (1 580MPa), but that of samples with volume fraction of 7% reduce rapidly to 1 220MPa. The reason for decreasing of fracture strength is that quenched-in crystals embedded on the amorphous matrix induce initiation and propagation of crack.

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[Bian Zan, He Guo, Chen Guoliang. Effect of Oxygen Impurity and Overheating on Microstructure and Mechanical Properties of As-cast Zr_(52.5)Cu_(17.9)Ni_(14.6)Al_(10)Ti_5 Bulky Glass Alloys[J]. Rare Metal Materials and Engineering,2001,(3).]
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