The silver-coated copper powders were prepared by a reduction method, using glucose as the reductant. The different adding processes of silver-ammonia solution varied the micro-morphology and appearance color of the powders. The coated powders were characterized by SEM and EDS. The silver contents of different adding processes were calculated by titration. Thus the optimal adding process was determined. Meanwhile, the silver coating deposit process was analyzed by observation of the powders taken out from the solution at different stages during silver plating.