+Advanced Search
Electrochemical Study on Electrodeposition of La3+ in EMIMBF4 Ionic Liquid
DOI:
Author:
Affiliation:

Clc Number:

Fund Project:

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
  • |
  • Comments
    Abstract:

    The electrodeposition of lanthanum on a Pt electrode was investigated in 0.01 mol/L LaCl3-0.1 mol/L LiCl-EMIMBF4 ionic liquid. The cyclic voltammetry, chronoamperometry and constant voltage electrolysis techniques were employed. The results of the cyclic voltammogram and the XRD pattern of deposits after electrolysis under constant voltage have supported a one step electrodeposition mechanism of lanthanum, La3+ + 3e-→La. The results also indicate that the reduction of La3+ ion is irreversible. The transfer coefficient and the diffusion coefficient of La3+ ion in 0.01 mol/L LaCl3-0.1 mol/L LiCl-EMIMBF4 ionic liquid are 0.0492 and (1.07-1.19)×10-6 cm2/s, respectively

    Reference
    Related
    Cited by
Get Citation

[Kim Pyonghun, Xie Hongwei, Gu Huimin, Zhai Yuchun. Electrochemical Study on Electrodeposition of La3+ in EMIMBF4 Ionic Liquid[J]. Rare Metal Materials and Engineering,2012,41(4):599~602.]
DOI:[doi]

Copy
Article Metrics
  • Abstract:
  • PDF:
  • HTML:
  • Cited by:
History
  • Received:April 19,2011
  • Revised:
  • Adopted:
  • Online:
  • Published: