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Effect of F Doping on Fabrication and Superconductivity of SmO1-xFδFeAs Compound
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National Basic Research Program of China (2006CB601005); National High Technology Research and Development Program of China (2009AA032401); National Natural Science Foundation of China (50771003 and 50802004); Beijing Municipal Natural Science Foundation (2092006)

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    Abstract:

    We report the effect of fluorine doping on the fabrication and superconductivity of the iron-based arsenic oxide SmO1-xFδFeAs (δ≥x) compound. The fluorine over-doping can greatly reduce the heat treatment temperature and the heat treatment time, meanwhile the superconductivity of the SmO1-xFδFeAs samples does not reduce. The critical transition temperature (Tc) is as high as 56.5 K for the SmO0.7F0.3FeAs sample prepared by the two-step solid state reaction method at 1120 °C for 40 h, the Jc of the sample is 2.4×105 A/cm2 (10 K, 0 T). Tc of the fluorine over-doped SmO0.7F0.35FeAs and SmO0.7F0.4FeAs samples prepared by the two-step solid state reaction method at 1100 °C for 20 h are 56 and 55 K, respectively. Jc of the both samples are 1.9×105 and 1.7×105 A/cm2 (10 K, 0 T), respectively.

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[Liu Zhiyong, Suo Hongli, Ma Lin, Zhao Junjing, Ni Baorong, Guo Zhichao, Yan Binjie, Liu Min, Wu Ziping, Zhou Meiling. Effect of F Doping on Fabrication and Superconductivity of SmO1-xFδFeAs Compound[J]. Rare Metal Materials and Engineering,2012,41(7):1144~1148.]
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  • Received:July 21,2011
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