Roll bonding technology is one of the main preparation technologies of the bimetal laminated composite plate, and the history of its research and application over 100 years. It includes many methods, such as cold-roll bonding, hot-roll bonging, explosive rolling bonding, asymmetric rolling bonding, and so on. Firstly, the surface treatment methods of the rolling pieces were briefly introduced. Then, the technics characterizations, interface bonding theories and application of the roll bonding technology were summarized. The research status of the hot-roll bonding method and the asymmetric rolling bonding method was elaborated, especially. Last, the prospect of the technology was outlook.