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Microstructure Evolution in Powder Metallurgy Al-Si-Cu Foam during Foaming Process
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1.Aerospace Institute of Advanced Materials Processing Technology;2.Faculty of Materials and Manufacturing,National Engineering Laboratory for Industrial Big-data Application Technology,Beijing University of Technology

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Fund Project:

National Natural Science Foundation of China (51671005), Beijing Natural Science Foundation (2202009).

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    Abstract:

    The microstructure evolution in Al-Si-Cu foam during foaming process was studied using the scanning electron microscope. Through mixing the powder to the composition of Al-6Si-5Cu-2TiH2-1.5MnO2 wt%, and using the hot pressure process at 500℃, the Al foam could be foamed homogeneously at 640℃ for 12-20min. The corresponding microstructure analysis showed that the sample before foaming contained spherical Si, Al2Cu, lump-shaped TiH2 and flat MnO2 phase. After foaming, the sample showed the millimeter-scale main hole with the sparse micrometer-scale pores inside the hole wall. The precipitates in hole wall were intragrain small Si and Al2Cu particles, and grain boundary eutectic Si and Al2Cu phases, as well as randomly distributed lump-like Al-Mn phase, MnO2 phase and spherical Ti-rich phase. Therein, the Ti-rich phase, formed by the reaction of liquid Al and TiH2 after release H2, exhibited two types of morphology. The first one consisted of a Ti core, a thin layer of τ2(Al14Ti33Si53) inner shell, and the mixed dendrite-like τ1(Al20Ti32Si48) and τ2 phases outer shell. The second type of morphology consisted of Ti core, and a mixed lump-like τ1and (Al,Si)3Ti shell. The composition of Si in the first type was much higher than that of the second type. That was mainly because the Si composition in liquid Al was not uniform due to the inheritance of the original microstructure of solid Al and Si, and the two types of Ti-rich phase formed in the Si rich and Si poor regions. The microstructure analysis of foaming process could be the foundation for designing the aging strengthening aluminum foam.

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[Ding Yusheng, Gao Kunyuan, Wang Huadong, Song Peng, Chen Ming, Liang Yueying, Peng Haichun. Microstructure Evolution in Powder Metallurgy Al-Si-Cu Foam during Foaming Process[J]. Rare Metal Materials and Engineering,2021,50(6):2134~2143.]
DOI:10.12442/j. issn.1002-185X.20200512

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History
  • Received:July 16,2020
  • Revised:September 30,2020
  • Adopted:October 15,2020
  • Online: July 07,2021
  • Published: June 30,2021