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Loading Mechanism and Loading Kinetics of TiO2 on Cordierite Surface by Chemical Vapor Deposition
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1.School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China;2.State Key Laboratory of Industrial Vent Gas Reuse, Southwest Research & Design Institute of Chemical Industry, Chengdu 610225, China

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Sponsored by State Key Laboratory of Industrial Vent Gas Reuse (SKLIVGR-SWPU-2020-04)

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    Abstract:

    In order to explore the loading mechanism and loading kinetics of TiO2 on cordierite, the acid-etched cordierite was used as the matrix and the TiO2 loading test was conducted by the chemical vapor deposition (CVD) method. The scanning electron microscope, energy disperse spectroscope, X-ray diffraction, and Brunauer-Emmett-Teller (BET) specific surface area measurement were used to characterize the TiO2 on cordierite surface and determine the loading speed at different temperatures. The results show that the surface of modified cordierite with TiO2 mainly consists of (211)-oriented and (200)-oriented anatase-TiO2 which is the octahedron and cube with BET specific surface area of 78.80 m2·g-1, an average pore diameter of 9.80 nm, and a bimodal distribution. The loading process is the diffusion and adsorption of TiCl4 and O2 towards the cordierite matrix. TiCl4 decomposes and Ti4+ enters the matrix lattice under the high oxygen potential to form TiO2 nuclei. After the preferential orientation and epitaxial growth, the loading deposition rate equation is , where T is the loading temperature and is the partial pressure when TiCl4 is in the gas phase.

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[Yang Mei, Liu Liangwen, Zheng Heng, Lu Jingxiang, Wang Jingyi. Loading Mechanism and Loading Kinetics of TiO2 on Cordierite Surface by Chemical Vapor Deposition[J]. Rare Metal Materials and Engineering,2022,51(3):778~782.]
DOI:10.12442/j. issn.1002-185X.20210062

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History
  • Received:January 21,2021
  • Revised:April 12,2021
  • Adopted:May 12,2021
  • Online: March 30,2022
  • Published: March 30,2022