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Effect of Trace Nickel Addition on Microstructure, Corrosion Resistance and Hydrogen Absorption of Zr-4 Alloy
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1.Centre of Excellence for Advanced Materials, Dongguan 523808, China;2.State Nuclear BaoTi Zirconium Industry Company, Baoji 721013, China

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Guangdong Innovative and Entrepreneurial Research Team Program (2016ZT06G025)

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    Abstract:

    Nickel as a trace element was added into zirconium alloy (Zr-4) and then alloy sheet samples were prepared. The microstructure, corrosion property, and hydrogen content of the Zr-4 alloy were studied. Results show that the steam corrosion resistance at 400 °C can be greatly improved by adding nickel from 0.001wt% (the content in the sponge zirconium) to 0.005wt%, and there is no obvious effect on hydrogen absorption property. Trace nickel addition increases the content of the second phase particles in the form of Zr(Fe, Ni)2 obviously, and promotes the aggregation of silicon around second phase particles, which can prevent or delay the oxidation of fine particles. In addition, zirconium tubes (Φ63.5 mm×10.92 mm) with the same alloy component also exhibit excellent nodular corrosion resistance and uniform corrosion resistance.

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[Chu Linhua, Zhang Shuyan, Yuan Gaihuan, Wu Guiyi. Effect of Trace Nickel Addition on Microstructure, Corrosion Resistance and Hydrogen Absorption of Zr-4 Alloy[J]. Rare Metal Materials and Engineering,2022,51(12):4488~4495.]
DOI:10.12442/j. issn.1002-185X.20220144

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History
  • Received:February 26,2022
  • Revised:December 02,2022
  • Adopted:March 18,2022
  • Online: January 11,2023
  • Published: December 30,2022