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Enhancement of Magnetic Properties and Corrosion Resistance for Misch Metal Based RE-Fe-B Magnets Prepared by Double Main Phase Process
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Affiliation:

1.School of Science, Inner Mongolia University of Science and Technology, Baotou 014010, China;2.School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, China;3.Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China

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National Key Research and Development Program of China (2022YFB3505800); Natural Science Foundation of Inner Mongolia (2022LH MS05006)

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    Abstract:

    In order to reduce the RE-Fe-B material cost and to balance the utilization of rare earth sources, [(Pr, Nd)1?xMMx]30.3(Fe, Co)bal- M0.73B0.98 (x =0.3, 0.5, 0.7, wt%) magnets were prepared by double main phase (DMP) and single main phase (SMP) processes. DMP magnets are superior to SMP magnets with the same nominal composition in magnetic properties and corrosion resistance. For x=0.5, the magnetic properties of DMP magnets are Br=1.308 T, Hcj=799.980 kA/m and (BH)max=325.6436 kJ/m3, which are higher than those for SMP magnets (Br=1.297 T, Hcj=746.8868 kA/m and (BH)max=317.8428 kJ/m3) with the same nominal composition, and the impro-ved RE-rich phase distribution and REs heterogeneity distribution are the main reasons. When DMP magnets are exposed to a hygro-thermal environment, there is not only RE-rich phase corrosion, but also pulverized main phase grain due to hydrogenation behavior difference between LaCe-rich and LaCe-lean shell-core within one individual grain. As a result, it is demonstrated that DMP techni-que is an effective approach to improve the permanent magnetic properties and corrosion resistance of MM-based sintered magnets.

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[Lian Xinli, Zhou Jianjun, Li Shilin, Zhao Yuanhong, Wang Changpeng, Wang Yin, Liu Fei, Zhang Ming, Zuo Jianhua, Bai Suo, Liu Yanli, Li Zhubai, Li Yongfeng. Enhancement of Magnetic Properties and Corrosion Resistance for Misch Metal Based RE-Fe-B Magnets Prepared by Double Main Phase Process[J]. Rare Metal Materials and Engineering,2024,53(3):660~666.]
DOI:10.12442/j. issn.1002-185X.20230230

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History
  • Received:April 21,2023
  • Revised:March 04,2024
  • Adopted:June 26,2023
  • Online: March 22,2024
  • Published: March 20,2024