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Effect of bimetal oxide doping on the aging performance of catalyzed DPF
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1.School of Automotive Studies,Tongji University;2.Beijing Municipal Ecological and Environmental Monitoring Center

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Fund Project:

National Natural Science Foundation of China (Project No. 52206167), Fundamental Research Funds for the Central Universities

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    Abstract:

    Based on XRD, XPS, H2-TPR and other characterization methods for physical and chemical properties and catalyst activity evaluation methods, the physical and chemical properties and catalytic activity of CDPF samples doped with different bimetal oxide under hydrothermal aging condition were studied. The results show that Ce-Zr bimetal oxide doped sample has good stability in phase structure and cell parameters, Zr-Fe bimetal oxide doped sample can better inhibit the dispersity of noble metal on carrier’s surface. For Fe-Ce and Zr-Fe bimetal oxide doped CDPF samples, during high-temperature aging process, the dispersed metal oxides undergo solid solution again, which will cause a formation of solid solution and more oxygen vacancies. After experiencing high-temperature hydrothermal aging process, the diffraction characteristic peaks of samples all migrate various degrees towards the high-temperature direction. Fe-Ce bimetal oxide doped sample shows a low degree of migration while Ce-Zr bimetal oxide doped sample is higher. Fe-Ce and Zr-Fe bimetal oxide doped aged samples showed higher oxidation activity of CO and show a low-level degradation. Ce-Zr bimetal oxide doped aged sample showed a slight decrease in the oxidation activity of C3H8. The catalytic activity for NO of Ce-Zr bimetal oxide doped sample decreases slightly after high-temperature hydrothermal aging process.

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[Zhang Yunhua, Zheng Sen, Lou Diming, Fang Liang, Feng Qian. Effect of bimetal oxide doping on the aging performance of catalyzed DPF[J]. Rare Metal Materials and Engineering,2024,53(5):1391~1400.]
DOI:10.12442/j. issn.1002-185X.20230334

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History
  • Received:May 31,2023
  • Revised:August 24,2023
  • Adopted:August 24,2023
  • Online: May 28,2024
  • Published: May 22,2024