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Design of α-type Titanium Alloys with Improved Corrosion Resistance and Tensile Properties
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1.School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043, China;2.Department of Mechanical Materials Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan;3.School of Mechanical Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043, China

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Natural Science Foundation of Hebei Province of China (E2021210114); Project of Hebei Province Department of Human Resources and Social Security of China (C20220325)

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    Abstract:

    Newly designed α-type titanium (α-Ti) alloys were proposed based on both electron parameters (bonding time Bot and d-orbital energy level Mdt). The newly designed α-Ti alloy Ti-5Al-4Zr-3.6Sn, modified alloy Ti-5Al-3Sn-1.9Zr, and reference alloy Ti-5Al-2.5Sn have the same Bot value of 3.847 and different Mdt values of 2.430, 2.426, and 2.422, respectively. The ultimate tensile strength (σUTS), fracture strain (?f), and hot salt corrosion resistance of the three α-Ti alloys were measured. The three α-Ti alloys were produced by the cold crucible levitation melting (CCLM) technique. Results show that homogeneous microstructures can be observed in three α-Ti alloys. The α mono-phase in three α-Ti alloys has the grain size of approximately 600 μm. σUTS and ?f of Ti-5Al-4Zr-3.6Sn alloy are 801 MPa and 16%, respectively; σUTS and ?f of Ti-5Al-3Sn-1.9Zr alloy are 708 MPa and 15%, respectively; σUTS and ?f of Ti-5Al-2.5Sn alloy are 603 MPa and 15%, respectively. After hot salt corrosion tests were conducted for 28.8 ks, the mass loss ratio of Ti-5Al-4Zr-3.6Sn, Ti-5Al-3Sn-1.9Zr, and Ti-5Al-2.5Sn alloys is 2.61%, 2.83%, and 3.10%, respectively. The results of σUTS, ?f, and hot salt corrosion resistance indicate that the newly designed alloy Ti-5Al-4Zr-3.6Sn has great potential for practical applications.

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[Ma Xilong, Kazuhiro Matsugi, Shang Zhifeng, Su Hongji, Jia Bowen, Nie Guoquan. Design of α-type Titanium Alloys with Improved Corrosion Resistance and Tensile Properties[J]. Rare Metal Materials and Engineering,2024,53(4):947~953.]
DOI:10.12442/j. issn.1002-185X.20230381

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History
  • Received:June 15,2023
  • Revised:August 24,2023
  • Adopted:August 29,2023
  • Online: April 23,2024
  • Published: April 23,2024