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Theory and Method of Transformative Metallurgy (Dissocia-tion and Purification) of Beryllium Ore
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1.State Key Laboratory for Advanced Iron and Steel Processes and Products, Central Iron and Steel Research Institute Co., Ltd, Beijing 100081, China;2.CISRI Sunward Technology Co., Ltd, Beijing 100081, China;3.China Minmetals Beryllium Co., Ltd, Hengyang 421513, China;4.Northwest Rare Metal Material Research Institute Ningxia Co., Ltd, Shizuishan 753000, China

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National Key Research and Development Program of China (2021YFC2902301, 2021YFC2902302)

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    Abstract:

    A transformative beryllium metallurgy theory and method was proposed based on the low-temperature dissociation of hydrofluoric acid and purification by exploiting the large difference of fluoride solubility. Hydrofluoric acid can quickly dissociate beryllium ore powder directly at low or room temperature with more than 99% dissociation rate. The solubility of AlF3, FeF3, CrF3, and MgF2 is low. Coupled with common ion effect, 99.9%-purity beryllium products can be prepared without chemical purification. For high-purity beryllium products of grade 4N or higher, they can be prepared through the superior property that the pH intervals of iron, chromium, and other hydroxide precipitates are distinctly different from those corresponding to Be(OH)2 precipitates. This new method can be used to prepare most of the beryllium products that are prepared by modern beryllium metallurgy.

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[Guo Peimin, Shen Yaozong, Wang Lei, Kong Lingbing, Wang Dongxin, Guo Qing. Theory and Method of Transformative Metallurgy (Dissocia-tion and Purification) of Beryllium Ore[J]. Rare Metal Materials and Engineering,2025,54(5):1207~1216.]
DOI:10.12442/j. issn.1002-185X.20240130

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History
  • Received:March 08,2024
  • Revised:April 16,2024
  • Adopted:April 18,2024
  • Online: May 23,2025
  • Published: May 22,2025