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Effects of Cu on Microstructure and Corrosion Behaviour of Hot-Rolled Mg-3Zn-1Y Alloys
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1.College of Chemical Engineering and Technology, Taiyuan University of Science and Technology, Taiyuan 030024, China;2.College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

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Fundamental Research Program of Shanxi Province (202203021222188, 202303021211166); Central Guiding Science and Technology Development of Local Fund (YDZJSK20231A046); Key Scientific Research Project in Shanxi Province (202102050201003, 202203D111001)

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    Abstract:

    The microstructure and corrosion behaviour of hot-rolled Mg-3Zn-1Y-xCu alloys (x=0, 1, 3, 5, wt%) were investigated. Results show that all Mg-3Zn-1Y-xCu alloys mainly consist of α-Mg matrix and Mg3Zn6Y phases. The addition of Cu element promotes the formation of MgZnCu phase, and the amount of MgZnCu phase is increased with the increase in Cu content. Electrochemical and immersion test results show that the corrosion resistance of Mg-3Zn-1Y-xCu alloys is deteriorated after Cu addition, which can be attributed to the influence of the microstructure of alloys and the properties of the formed corrosion product film. The MgZnCu phase with high electrochemical potential accelerates the micro-galvanic corrosion as strong cathodic sites, and the decreased protection effect of the corrosion product ?lm results from the variation in PBR value of the related compounds.

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[Zhang Yuezhong, Chen Xiaoting, Shen Jing, Wu Pengpeng, Zhang Shaohua, Liu Baosheng. Effects of Cu on Microstructure and Corrosion Behaviour of Hot-Rolled Mg-3Zn-1Y Alloys[J]. Rare Metal Materials and Engineering,2024,53(10):2794~2804.]
DOI:10.12442/j. issn.1002-185X.20240299

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History
  • Received:May 17,2024
  • Revised:June 07,2024
  • Adopted:June 14,2024
  • Online: September 27,2024
  • Published: September 27,2024