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Influence of N2 Flow Rate on Microstructure and Corrosion Resistance of TaN Coatings on Bipolar Plates of PEM Electrolyser
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1.State Key Laboratory for Mechanical Behavior of Materials, Xi 'an Jiaotong University, Xi 'an 710049, China;2.Western Metal Materials Co., Ltd, Xi 'an 710201, China

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National Key Research and Development Program of China (2022YFB4002100); National Natural Science Foundation of China (52271136); Natural Science Foundation of Shaanxi Province (2021JC-06)

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    Abstract:

    TaN coatings were deposited on Ti bipolar plates by magnetron sputtering to improve corrosion resistance and service life. The influence of N2 flow rate on the surface morphology, hydrophobicity, crystallinity, corrosion resistance, and interfacial contact resistance of TaN coatings was studied. Results show that as the N2 flow rate increases, the roughness of TaN coatings decreases firstly and then increases, and the hydrophobicity increases firstly and then decreases. At the N2 flow rate of 3 mL/min, TaN coating with larger grain size presents lower roughness and high hydrophobicity. The coating possesses the lowest corrosion current density of 2.82 μA·cm-2 and the highest corrosion potential of -0.184 V vs. SCE in the simulated proton exchange membrane water electrolyser environment. After a potentiostatic polarization test for 10 h, a few corrosion pits are observed on the TaN coatings deposited at an N2 flow rate of 3 mL/min. After 75 h of electrolytic water performance testing, the TaN coating on bipolar plate improves the corrosion resistance and thus enhances the electrolysis efficiency (68.87%), greatly reducing the cost of bipolar plates.

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[Gao Jianping, Lv Yuanjiang, Li Yongjing, Sun Wenqian, Ren Biying, Dai Zhengfei, Ma Fei. Influence of N2 Flow Rate on Microstructure and Corrosion Resistance of TaN Coatings on Bipolar Plates of PEM Electrolyser[J]. Rare Metal Materials and Engineering,2025,54(5):1127~1133.]
DOI:10.12442/j. issn.1002-185X.20240720

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History
  • Received:November 04,2024
  • Revised:December 05,2024
  • Adopted:January 03,2025
  • Online: May 23,2025
  • Published: May 22,2025