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Study of Electrochemical Properties of Ti/SnO2+MnOx/PbO2 Electrode Doped with Rare Earth Y
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    Abstract:

    Acid-proof Ti/SnO2+MnOx/PbO2 anode doped with rare earth Y was prepared by thermal decomposition method and electrodeposited method. The surface characterization of the electrode was characterized by scanning electron microscopy(SEM) and the element composition of layers was analyzed with X-ray Diffraction(XRD). The electrode electrochemical properties were analyzed with Cyclic Voltammogram (CV) and Electrochemical Impedance Spectroscopic (EIS).The influence of Y doping on the service life of the electrode in strong acid solution was emphatically studied. The results indicated that the semiconductive solid solution was formed between Y2O3 and SnO2, which maked the service life of electrode reaching 70 h in high electric density(4 A/cm2); At the same time the oxygen evolution reaction(OER) potential of this electrode reached 2.1 V . The rougher of the surface was, the better its electric catalytic properties were. Ti/SnO2+Y2O3+MnOx/PbO2 electrode is an ideal acid-proof anode material

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[Chu Qiuxia, Liang Zhenhai, Sun Yanfa, Wang Rongpeng, Fan Caimei. Study of Electrochemical Properties of Ti/SnO2+MnOx/PbO2 Electrode Doped with Rare Earth Y[J]. Rare Metal Materials and Engineering,2009,38(5):821~825.]
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  • Received:June 17,2008
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