A novel type of ceramic composite armor, metal-encased SiC ceramic armor with interpenetrating structure, was fabricated using a composite process, including preparation of reaction bonded SiC ceramic plate with ordered holes and metal casting of the macro-porous ceramic plate. The interface microstructures and elemental distributions or compositions of three different metals (a steel and two Ti alloys)/SiC composite armors were analyzed by scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). Relatively good interfacial bonding between ceramic and metal components was obtained, which is closely related to interfacial interactions and compressive residual stress on the ceramic during the cooling stage of casting. The interface microstructures depend significantly on the metal component composition (including the main element and the state of its existence after casting) and the casting process.