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Hydrogen-induced Amorphization in LaNi2.5M0.5 (M=Ni, Fe, Mn, Si) Alloys
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    Abstract:

    Effects of Fe, Mn and Si on the hydrogen-induced amorphization in LaNi3 were investigated by XRD and electrochemical method. All the LaNi2.5M0.5 (M = Ni, Fe, Mn and Si) alloys were prepared by melt-spun plus annealing method and their main phase is LaNi3. It is found that the hydrogen-induced amorphization appears in all the alloys for the first charging cycle. During the discharge process, no plateau is observed in LaNi3 and LaNi2.5Fe0.5 but a plateau in LaNi2.5Mn0.5 and LaNi2.5Si0.5, indicating that a small amount of Mn and Si suppresses the tendency of hydrogen-induced amorphization.

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[Wang Wei, Chen Yungui, Wu Chaoling. Hydrogen-induced Amorphization in LaNi2.5M0.5 (M=Ni, Fe, Mn, Si) Alloys[J]. Rare Metal Materials and Engineering,2011,40(12):2080~2082.]
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  • Received:December 21,2010
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