In the investigation of AgCuO composites, we have found a type of copper oxide particles with a superplastic deformability behavior, which is similar to that of metals. To find the reason of the deformability of the copper oxide particles. SEM, STEM and TEM were used to analyze their crystal structures in AgCuO composites, The results show that the copper oxide particles with micro-superplasticity in the composites have cubic crystal structure, and their maximum elongation can be up to 300%, The copper oxide particles with no micro-superplasticity in the composites have monoclinic crystal structure. But the micro-superplastic behavior and mechanism of the copper oxides with the cubic crystal structure are not clear for the time being, the further investigation could be needed