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Investigation of Microstructures of Pt+Hf Modified γ-Ni+γ′-Ni3Al Coatings and Their Oxidation Resistance
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    Abstract:

    The Pt and Hf modified γ-Ni+γ′-Ni3Al coatings were fabricated on the DZ417G superalloy substrates by combined aluminizing and hafnizing using a pack cementation. During the co-deposition process, the phase structure formed on the coating surface changes with the increasing of hafnium contents in packs. When the hafnium contents are 2 wt%, 6 wt% and 12 wt% the coatings consist of the γ-Ni+γ′-Ni3Al, b-NiAl+Al16Hf6Ni7, and Al16Hf6Ni7, respectively. During post heat treatment the β-NiAl+Al16Hf6Ni7 and Al16Hf6Ni7 coatings are transformed to γ-Ni+γ′-Ni3Al and γ-Ni+γ′-Ni3Al+Al3HfNi12. Isothermal oxidation tests at 1100 ℃ for 10 h show that there are a lot of spallation on the surface of the substrate without coating, while the Pt and Hf modified γ-Ni+γ′-Ni3Al coating formed in the packs with 2 wt% Hf remains to be integrated after being oxidized for 30 h. The addition of the reactive element hafnium makes a further improvement on the oxidation resistance of the Pt+γ-Ni+γ′-Ni3Al coatings

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[Yao Peipei, Fu Chao, Cao Guanghui. Investigation of Microstructures of Pt+Hf Modified γ-Ni+γ′-Ni3Al Coatings and Their Oxidation Resistance[J]. Rare Metal Materials and Engineering,2014,43(1):224~228.]
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History
  • Received:December 17,2012
  • Revised:
  • Adopted:
  • Online: April 16,2014
  • Published: