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周芳,刘其斌,李栋梁.激光熔覆MoFeCrTiWSix多主元合金涂层组织和性能研究[J].稀有金属材料与工程(英文),2017,46(12):3941~3946.[Zhou Fang,Liu Qibin,Li Dongliang.Study of microstructure and properties of laser cladding MoFeCrTiWSix multi-principal element alloy coatings[J].Rare Metal Materials and Engineering,2017,46(12):3941~3946.]
Study of microstructure and properties of laser cladding MoFeCrTiWSix multi-principal element alloy coatings
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Received:October 04, 2015  Revised:November 29, 2015
Key words: laser cladding  multi-principal element alloy coatings  microstructure  properties
Foundation item:国家自然科学基金(51362004)、贵州省高层次创新型人才培养项目(黔科合人才[2015]4009号)、贵州省科技厅联合基金(黔科合LH字[2014]7605)
Author NameAffiliationE-mail
Zhou Fang Guizhou University zhoufang_1974@sina.com 
Liu Qibin 贵州大学材料与冶金学院 qbliu2@263.net 
Li Dongliang 贵州大学材料与冶金学院  
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      MoFeCrTiWSix (x=0, 0.2, 0.4, 0.6, 0.8, 1.0) multi-principal element alloy coatings were fabricated on Q235 steel by laser cladding. The effect of silicon on the microstructure, phases, microhardness and high-temperature oxidation resistance were investigated systematically by X-ray diffraction (XRD), scanning electron microscopy (SEM) and microhardness tester etc. The results show that, the phase of laser cladding MoFeCrTiW multi-principal element alloy coating is single BCC structure and its microstructure is equiaxed grains. The main phase is still BCC structure after adding different content of silicon into coating. When the content of silicon is no less than 0.4 moles, there exits small intermetallic compound in the coatings, the microstructures of coatings are composed of proeutectic BCC phase and eutectic structure of BCC phase and Cr5Fe50Mo8.9Si5.2Ti20.4 phase. With the content of silicon increasing, the morphology of proeutectic phase changes from cystiform-dendritic to columnar dendrites and equiaxed dendrites, while the content of eutectic structure is increased gradually. From the surface to bonding zone of coatings, the distribution of the mixing entropy changes from high entropy to medium entropy. With the addition of silicon, the microhardness and high-temperature oxidation at 900℃ of coatings are increased. When x is 1.0 mole, both the microhardness and the high-temperature oxidation resistance are the highest.