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卫英慧,王海洋,梁苗苗,侯利锋,李永刚,郭春丽.超疏水镁合金制备及其耐腐蚀性研究[J].稀有金属材料与工程(英文),2017,46(12):4006~4011.[Yinghui Wei,Haiyang Wang,Miaomiao Liang,Lifeng Hou,Yonggang Li,Chunli Guo.Research on Preparation and Corrosion-reistance of Super-hydrophobic Mg alloys[J].Rare Metal Materials and Engineering,2017,46(12):4006~4011.]
Research on Preparation and Corrosion-reistance of Super-hydrophobic Mg alloys
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Received:October 12, 2015  Revised:March 10, 2016
Key words: Mg alloy  surface modification  super-hydrophobic
Foundation item:国家自然科学基金资助 (51374151,21201129)
Author NameAffiliationE-mail
Yinghui Wei Shanxi Institute of Technology yhwei_tyut@126.com 
Haiyang Wang Taiyuan University of Technology  
Miaomiao Liang Taiyuan University of Technology  
Lifeng Hou Taiyuan University of Technology  
Yonggang Li Taiyuan University of Technology  
Chunli Guo Taiyuan University of Technology  
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      Four simple methods of fabricating a super-hydrophobic film on magnesium alloy through the employment of two chemical reagents and two surface modifiers are reported in the paper. The Mg alloys are chemically etched by CuCl2 or ZnSO4 first and then modified with low surface energy material of oleic acid or stearic acid. After modification, the obtained samples show super-hydrophobicity with static contact angle to reach more than 150 ° and the sliding angle of about 6.5 °. The super-hydrophobicity of obtained samples are stable; the water contact angle remains above 150 ° after being exposed in air for six months. Compared with the electrochemical properties of four super-hydrophobic samples, it can be found that the sample that is etched by CuCl2 and then self-assembled by stearic acid has the best corrosion resistance with the corrosion potential Ecorr improved by 0.33V, reaching to -1.11V. The diameter of capacitive arc is also 6-7 times than substrate.