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谢伟滨,王强松,解国良,刘冬梅,米绪军,高学成.Cu-20Ni-20Mn合金连续/不连续时效析出及其相互作用研究[J].稀有金属材料与工程(英文),2017,46(12):3799~3804.[Xie Weibin,Wang Qiangsong,Xie Guoliang,Liu Dongmei,Mi Xujun,Gao Xuecheng.Research of Interaction between Continuous and Discontinuous Precipitation in Cu-20Ni-20Mn Alloy[J].Rare Metal Materials and Engineering,2017,46(12):3799~3804.]
Research of Interaction between Continuous and Discontinuous Precipitation in Cu-20Ni-20Mn Alloy
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Received:October 27, 2015  Revised:December 22, 2015
Key words: Cu-Ni-Mn alloy  continuous precipitation  discontinuous precipitation  activation energy for grain boundary chemical diffusion
Foundation item:国家自然科学基金项目(项目号51401026)
Author NameAffiliationE-mail
Xie Weibin General Research Institute for Nonferrous Metals x881109100@163.com 
Wang Qiangsong General Research Institute for Nonferrous Metals wangqiangsongbj@163.com 
Xie Guoliang General Research Institute for Nonferrous Metals  
Liu Dongmei General Research Institute for Nonferrous Metals  
Mi Xujun General Research Institute for Nonferrous Metals  
Gao Xuecheng 北京有色金属研究总院  
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      The discontinuous and continuous precipitation behavior, and the interaction between them during the aging process in a Cu-20Ni-20Mn alloy have been investigated in the temperature range 573 K-698 K by scanning electron microscope (SEM), transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS). The results show that discontinuous precipitation is the predominant mechanism at 623 K and below, whereas both discontinuous and continuous precipitations occur when the temperature is higher than 673 K. The discontinuous precipitations with a lamellar mixed structure, consisting of alternate lamellae of matrix and NiMn phase, nucleate and grow preferentially on grain boundaries during the aging process. Continuous precipitations can either partially or completely inhibit the growth of discontinuous precipitation colonies. Obvious inhibition action on the migration of reaction front of discontinuous precipitation colonies are found by experimental results, owing to the continuous precipitates when their diameters reach up to about 5 nm or larger. The grain boundary chemical diffusion triple product sδDb is calculated according to an Aaronson-Liu model. In addition, the activation energy for discontinuous precipitation is determined to be in range between 106.7 to 113.5 kJ/mol based on Arrhenius equation, well below the activation energy for volume-bulk diffusion of Ni and Mn in Cu-rich alloy, indicating that discontinuous precipitation is easy to occur in grain boundaries.