The novel IrO2-CeO2-G/Ti composite electrodes were prepared by thermal decomposition method. The synthesized electrodes with different IrO2 content had been characterized by scanning electron microscope(SEM), transmission electron microscope(TEM), X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The electrochemical performances of the electrodes were investigated by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy in 0.5 M H2SO4 solution. The results showed that the electrode with 2.5mg/cm2 IrO2 exhibited an excellent specific capacitance value of 459.5 F/g, and the specific capacitance maintained about 97.8% after 5000 charge-discharge cycles at a 5mA/cm2 current density. The electrode with 2.5mg/cm2 IrO2 was an ideal electrode for supercapacitor due to?its unique composition proportion and the excellent pseudocapacitance property.