+Advanced Search
Microstructure and Magnetocaloric Effect of Spark Plasma Sintered LaFeSi Magnets with LaAl Addition
Author:
Affiliation:

1.School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China;2.School of Aeronautical Manufacturing Engineering, Nanchang Hangkong University, Nanchang 330063, China

Clc Number:

Fund Project:

National Natural Science Foundation of China (51961027, 51564037, 51401103); Key Research and Development Program of Jiangxi Province (20181ACE50005, 20192ACB50020); Postgraduate Innovation Special Fund of Jiangxi Province (YC2019005)

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
  • |
  • Comments
    Abstract:

    Using LaFe11.3Si1.7 and La0.77Al0.23 alloys as precursors, the bulk LaFeSi samples with excellent magnetocaloric performance were synthesized through the spark plasma sintering (SPS) technology. The results show that the La0.77Al0.23 compound with a low melting point is helpful in facilitating peritectic reaction, and NaZn13-type phase with high content can be achieved. A slight itinerant-electron-metamagnetic transition is observed. The increased thermal annealing time facilitates magnetic transition from the first order to the second order, which is ascribed to the excessive Al diffusion into the 1:13 phase. Under the thermal treatment condition of 1000 °C/6 h, the maximum entropy change (-ΔSM) max of 12.40 J?kg-1?K-1 can be obtained, and the highest refrigerating capacity, up to 318.40 J?kg-1, is achieved under thermal annealing condition of 1000 °C/10 h.

    Reference
    Related
    Cited by
Get Citation

[Fu Xiaokun, Shu Rong, Hou Yuhua, Liu Yanying, Huang Youlin, Li Wei, Fan Wenbing. Microstructure and Magnetocaloric Effect of Spark Plasma Sintered LaFeSi Magnets with LaAl Addition[J]. Rare Metal Materials and Engineering,2022,51(4):1239~1244.]
DOI:10.12442/j. issn.1002-185X.20210069

Copy
Article Metrics
  • Abstract:
  • PDF:
  • HTML:
  • Cited by:
History
  • Received:January 22,2021
  • Revised:April 28,2021
  • Adopted:May 12,2021
  • Online: April 28,2022
  • Published: April 28,2022