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Effect of Er on Amorphous Forming Ability and Mechanical Properties of Zr-based Alloys
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Affiliation:

1.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;2.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;3.School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou 730050

Clc Number:

TG139

Fund Project:

National Natural Science Foundation of China (51971103, 51861021); Key R&D Program of Gansu Province (20YF8GA052)

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    Abstract:

    The (Zr0.55Cu0.3Al0.1Ni0.05)100-xErx (x=0, 0.5, 1, 2, 3, 4, 5) Zr-based bulk alloy with diameter of 3 mm was prepared by water-cooled copper crucible smelting and copper mold suction casting using zirconium sponge as raw material. By comparing the microstructure and mechanical properties of sponge Zr-based alloy with different Er contents, the influence of Er on the amorphous forming ability, thermal stability, and mechanical properties of Zr-based bulk alloy was studied. Results show that when the zirconium sponge is used as the raw material, the amorphous formation ability and mechanical properties of sponge Zr-based alloy are obviously reduced. The sponge Zr-based amorphous alloy cannot be prepared when x=0. After adding Er element, the amorphous forming ability and mechanical properties of the sponge Zr-based alloy with the amorphous structure are improved obviously. The optimal mechanical properties of the sponge Zr-based alloy are achieved when x=2: the compression strength σbc is 2142.5 MPa and the plastic strain εp is 10.01% at room temperature. Compared with the amorphous (Zr0.55Cu0.3Al0.1Ni0.05)98Er2 alloy with the diameter of 3 mm prepared from high-purity Zr, the compressive strength and plasticity at room temperature of the sponge Zr-based alloy recovers by 97.63% and 69.95%, respectively. The Er addition is beneficial to improve the amorphous forming ability and mechanical properties of sponge Zr-based alloy, which also provides a new approach for low-cost preparation of Zr-based amorphous alloy.

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[fuxiaoqiang, koushengzhong, lixiaocheng, dingruixian, lichunyan, lichunling. Effect of Er on Amorphous Forming Ability and Mechanical Properties of Zr-based Alloys[J]. Rare Metal Materials and Engineering,2022,51(9):3159~3165.]
DOI:10.12442/j. issn.1002-185X.20210673

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History
  • Received:July 26,2021
  • Revised:September 09,2021
  • Adopted:September 09,2021
  • Online: September 30,2022
  • Published: September 27,2022