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Evolution of Co3Sn2 Phase Growth Morphology in Under-cooled Solidification of Co-Sn Single Phase Alloy
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School of Materials Science and Engineering, Lanzhou Jiao Tong University, Lanzhou 730070, China

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Gansu Province Science Foundation for Youths (20JR10RA268); Research Fund of Gansu Education Department (2021B-101); Tianyou Youth Talent Lift Program of LZJTU

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    Abstract:

    The undercooled solidification of (Co60Sn40)100-xNbx(x=0, 0.4, 0.6, 0.8, at%) single phase alloys was performed to investigate the changes of Co3Sn2 phase growth morphology.Results show that the Co3Sn2 phase grows with fractal seaweed morphology at small undercooling (x=0, 0.4), and transits to dendrite as the content of added Nb increases to 0.6at%, and then returns to fractal seaweed (x=0.8) as a response to the changes in interfacial energy anisotropy and kinetic anisotropy. With the increase in undercooling, the growth morphology of Co3Sn2 phase in (Co60Sn40)99.4Nb0.6 alloys returns from dendrite back to factual seaweed at undercooling larger than 28 K and then transits to compact seaweed at undercooling more than 143 K. The minor Nb addition slightly increases the growth velocity of Co3Sn2 phase at low and intermediate undercooling but obviously decreases the growth velocity at large undercooling. The sharp increase in the growth velocity is corresponding to the transition of Co3Sn2 phase growth morphology from fractal seaweed to compact seaweed.

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[Kang Jilong, Ma Zhiyao, Li Zhengning, Chu Ke. Evolution of Co3Sn2 Phase Growth Morphology in Under-cooled Solidification of Co-Sn Single Phase Alloy[J]. Rare Metal Materials and Engineering,2023,52(10):3410~3416.]
DOI:10.12442/j. issn.1002-185X.20230069

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History
  • Received:February 11,2023
  • Revised:April 20,2023
  • Adopted:April 27,2023
  • Online: October 26,2023
  • Published: October 24,2023