+Advanced Search
Effect of Palladium Electroplating on Hydrogen Absorption Properties of Zirconium Alloy
Author:
Affiliation:

1.State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;2.CNPC Engineering Technology R&D Company Limited, Beijing 102206, China;3.Whole Win (Beijing) Materials Sci. and Tech. Co., Ltd, Beijing 102100, China

Clc Number:

Fund Project:

National Natural Science Foundation of China (21171018, 51271021); Supported by State Key Laboratory for Advanced Metals and Materials (2019-ZD06, 2021Z-18)

  • Article
  • |
  • Figures
  • |
  • Metrics
  • |
  • Reference
  • |
  • Related
  • |
  • Cited by
  • |
  • Materials
  • |
  • Comments
    Abstract:

    Zirconium is an excellent hydrogen absorption material and has been regarded as a candidate material in the deuterium storage field. However, due to its higher hydrogen absorption temperature and slower hydrogen absorption kinetics, it cannot be applied at present. Palladium electroplating was used as a surface modification to improve the property. The results show that after the palladium electroplating and annealing, the zirconium alloy can absorb hydrogen at room temperature with an appropriate incubation period. With the increase in temperature, the hydrogen absorption rate becomes faster with a shorter incubation period. A transition zone forms between the palladium layer and zirconium substrate, and PdH1.33 and H0.62Zr0.38 are found in the transition zone after hydrogenation. These hydride phases in the transition zone play an important role in improving the hydrogen absorption property of zirconium. For the kinetics mechanism, it is determined to be 1-D diffusion at room temperature and 2-D diffusion at 250 °C.

    Reference
    Related
    Cited by
Get Citation

[Zhao Ligong, Li Jianghao, Guo Huijuan, Yang Dawen, Zhang Anjia, Zhang Peilong, Zhou Wenjiao, Tong Huan, Song Xiping. Effect of Palladium Electroplating on Hydrogen Absorption Properties of Zirconium Alloy[J]. Rare Metal Materials and Engineering,2024,53(3):685~691.]
DOI:10.12442/j. issn.1002-185X.20230102

Copy
Article Metrics
  • Abstract:
  • PDF:
  • HTML:
  • Cited by:
History
  • Received:March 01,2023
  • Revised:July 24,2023
  • Adopted:July 24,2023
  • Online: March 22,2024
  • Published: March 20,2024