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Preparation and lattice thermal expansion of lanthanum magnesium hexaaluminate powder with magnetoplumbite structure
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Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgy Mineral Resources,Wuhan University of Science and Technology,The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,,Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgy Mineral Resources,Wuhan University of Science and Technology

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    Abstract:

    The lanthanum magnesium hexaaluminate (LaMgAl11O19) powder was prepared via reverse chemical coprecipitation and high-temperature calcination method. The phase composition, microstructure, crystal structure and anisotropic lattice thermal expansion were ananlyzed using X-ray diffractometer (XRD), field emission scanning electron microscope (FSEM), in-situ high temperature X-ray diffraction (HD-XRD) and Rietveld refnement. The results showed that the precursors were final transformed to LaMgAl11O19 at sintering temperature of 1600 oC, in which the hexagonal plane was regular and smooth. Anisotropic lattice thermal expansion of LaMgAl11O19 was investigated by HD-XRD using rietveld refnement method. The influence of temperature-related parameter on cell parameters was analyzed, of which aT=5.5821+1.625×10-5T+1.757×10-8T2+4.24×10-12T3 and cT=21.9189+1.1952×10-4T+4.587×10-8T2+5.463×10-11T3. Lattice thermal expansion of LaMgAl11O19 presented anisotropic characteristics. At ambient temperature to 1300 ℃, average coefficient of thermal expansion of LMA were obtained with TECs(//a)= 8.42×10-6 /℃, TECs(//c)=12.54×10-6 /℃. The variation of lattice thermall expansion of LaMgAl11O19 mainly due to the changes of La-O bond caused by temperatute.

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[Hongdan Wu, Jinhua Zhang, Xinrong Lei, Zhihui Zhou. Preparation and lattice thermal expansion of lanthanum magnesium hexaaluminate powder with magnetoplumbite structure[J]. Rare Metal Materials and Engineering,2018,47(S1):59~62.]
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History
  • Received:May 26,2017
  • Revised:February 06,2018
  • Adopted:February 07,2018
  • Online: October 22,2018
  • Published: