钛基储氢合金的研究进展
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西北有色金属研究院

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TG146.23

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Progress on Ti-based Hygrogen Storage Alloy
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Northwest Institute for Nonferrous Metal Research

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    摘要:

    Ti基储氢合金储氢性能较好、成本低、储氢系统设计简单,因而备受关注;但其不足之处是平台压普遍较高、不易活化、传热速度慢、易受杂质气体毒化等。以提高合金氢化物热力学稳定性和储氢量为出发点,本文简述了Ti-Fe、 Ti-Cr、Ti-Mn、Ti-Zr、Ti-V、Ti-Ni系钛基储氢合金的研究进展,重点阐述了元素的置换或添加、制备工艺及热处理等对钛基合金储氢性能的影响,同时简述了提升钛基储氢合金活化性能的方法与措施,并对钛基储氢合金的发展前景进行了展望。

    Abstract:

    Ti-based hydrogen storage alloys have attracted much attention because of their good hydrogen storage performance, low cost and simple design for hydrogen storage system. However, its shortcomings are relatively high platform pressure, not easy to be activated, slow heat transfer speed, easy to be poisoned by impurity gases, etc. In order to improve the thermodynamic stability and hydrogen storage capacity of alloy hydrides, research progress of Ti-Fe, Ti-Cr, Ti-Mn, Ti-Zr, Ti-V, Ti-Ni based titanium hydrogen storage alloys is reviewed in this paper, focusing on the effects of element replacement or addition, manufacturing process and heat treatment on the hydrogen storage properties of titanium-based alloys. Methods and measures to improve the activation performance of titanium-based hydrogen storage alloys are also presented. At last future developments of titanium-based hydrogen storage alloys are prospected.

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  • 收稿日期:2022-07-22
  • 最后修改日期:2022-08-31
  • 录用日期:2022-09-02
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